This behaviour started after the latest kernel upgrade.
Systemd-analyze shows powerdevil taking a while.
21.519s plasma-powerdevil.service
1.454s xdg-desktop-portal.service
951ms plasma-kcminit.service
Journalctl mentions a few things
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Service file '/usr/share//dbus-1/services/org.kde.dolphin.FileManager1.service' is not named after the D-Bus name 'org.freedesktop.FileManager1'.
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Service file '/usr/share//dbus-1/services/org.kde.kscreen.service' is not named after the D-Bus name 'org.kde.KScreen'.
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Policy to allow eavesdropping in /usr/share/dbus-1/session.conf +31: Eavesdropping is deprecated and ignored
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Policy to allow eavesdropping in /usr/share/dbus-1/session.conf +33: Eavesdropping is deprecated and ignored
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Service file '/usr/share//dbus-1/services/org.kde.plasma.Notifications.service' is not named after the D-Bus name 'org.freedesktop.Notifications'.
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Service file '/usr/share//dbus-1/services/org.xfce.Thunar.FileManager1.service' is not named after the D-Bus name 'org.freedesktop.FileManager1'.
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Ignoring duplicate name 'org.freedesktop.FileManager1' in service file '/usr/share//dbus-1/services/org.xfce.Thunar.FileManager1.service'
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Service file '/usr/share//dbus-1/services/org.xfce.Tumbler.Cache1.service' is not named after the D-Bus name 'org.freedesktop.thumbnails.Cache1'.
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Service file '/usr/share//dbus-1/services/org.xfce.Tumbler.Manager1.service' is not named after the D-Bus name 'org.freedesktop.thumbnails.Manager1'.
jul 19 10:10:17 mooty-b550visiond dbus-broker-launch[1129]: Service file '/usr/share//dbus-1/services/org.xfce.Tumbler.Thumbnailer1.service' is not named after the D-Bus name 'org.freedesktop.thumbnails.Thumbnailer1'.
jul 19 10:10:48 mooty-b550visiond systemd[1100]: Finished Splash screen shown during boot.
jul 19 10:11:10 mooty-b550visiond kdeconnectd[1597]: 2024-07-19T10:11:10 kdeconnect.core: Could not query capabilities from notifications server
jul 19 10:11:49 mooty-b550visiond systemd[1100]: plasma-powerdevil.service: start operation timed out. Terminating.
jul 19 10:11:49 mooty-b550visiond systemd[1100]: plasma-powerdevil.service: Failed with result 'timeout'.
jul 19 10:11:49 mooty-b550visiond systemd[1100]: Failed to start Powerdevil.
jul 19 10:11:49 mooty-b550visiond systemd[1100]: Reached target KDE Plasma Workspace.
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: busno=4, sleep-multiplier = 2,00. Testing for supported feature 0x10 returned Error_Info[DDCRC_RETRIES in ddc_write_read_with_retry, causes: DDCRC_READ_ALL_ZERO(10)]
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: busno=7, Feature 0xdd should not exist but ddc_get_nontable_vcp_value() succeeds, returning mh=0x00 ml=0x64 sh=0x00 sl=0x64
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: busno=7, Feature 0x41 should not exist but ddc_get_nontable_vcp_value() succeeds, returning mh=0x00 ml=0x64 sh=0x00 sl=0x64
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: busno=7, Feature 0x00 should not exist but ddc_get_nontable_vcp_value() succeeds, returning mh=0x00 ml=0x64 sh=0x00 sl=0x64
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: busno=7, All features that should not exist detected. Monitor does not indicate unsupported
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: Library initialization complete.
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: Watch thread started
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: org.kde.powerdevil: org.kde.powerdevil.chargethresholdhelper.getthreshold failed "Charge thresholds are not supported by the kernel for this hardware"
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: org.kde.powerdevil: org.kde.powerdevil.backlighthelper.brightness failed
jul 19 10:12:10 mooty-b550visiond systemd[1100]: Started Powerdevil.
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: org.kde.powerdevil: Handle button events action could not check for screen configuration
jul 19 10:12:10 mooty-b550visiond org_kde_powerdevil[1766]: org.kde.powerdevil: org.kde.powerdevil.chargethresholdhelper.getthreshold failed "Charge thresholds are not supported by the kernel for this hardware"
jul 19 10:12:12 mooty-b550visiond org_kde_powerdevil[1766]: Sleep event. connector=card1-DP-3, dref not set
jul 19 10:12:14 mooty-b550visiond systemd[1100]: Started Konsole - Terminal.